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Exploitation of the photochromic nitroprusside anion [FeNO(CN)5]2- as counterion for constructing molecular conductors: The first radical cation salts based on BDH-TTP and the amide functionalized derivatives of EDT-TTF

Abstract : The radical cation salts based on BDH-TTP and the mono- and diamide functionalized derivatives of EDT-TTF with the double charged nitroprusside anion [FeNO(CN)5]2- (NP): kappa -(BDH-TTP)4[NP]C6H5NO2 (1), kappa -(BDH-TTP)4[NP] (2), (BDH-TTP)2[NP] (3), alpha-[ EDT-TTF-CONH 2]4[NP] (4), beta -[ EDT-TTF-(CONH2)2]2[NP] 0.5(C6H5NO2)0.5 (5) have been synthesized. The crystal structures and transport properties of 1 - 5, as well as electronic band structures of 1and 2 have been studied.
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https://hal.univ-angers.fr/hal-02542302
Contributeur : Cécile Meziere <>
Soumis le : mardi 14 avril 2020 - 16:15:55
Dernière modification le : mardi 14 juillet 2020 - 11:04:09

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R. Shibaeva, S. Khasanov, L. Zorina, S. Simonov, I. Shevyakova, et al.. Exploitation of the photochromic nitroprusside anion [FeNO(CN)5]2- as counterion for constructing molecular conductors: The first radical cation salts based on BDH-TTP and the amide functionalized derivatives of EDT-TTF. Journal de Physique 4, EDP Sciences, 2004, 114, pp.481-485. ⟨10.1051/jp4:2004114112⟩. ⟨hal-02542302⟩

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