Exploitation of the photochromic nitroprusside anion [FeNO(CN)5]2- as counterion for constructing molecular conductors: The first radical cation salts based on BDH-TTP and the amide functionalized derivatives of EDT-TTF

R. Shibaeva; S. Khasanov; L. Zorina; S. Simonov; I. Shevyakova; L. Kushch; L. Buravov; E. Yagubskii; S. Baudron; C. Meziere; P. Batail; J. Yamada

doi:10.1051/jp4:2004114112

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Exploitation of the photochromic nitroprusside anion [FeNO(CN)5]2- as counterion for constructing molecular conductors: The first radical cation salts based on BDH-TTP and the amide functionalized derivatives of EDT-TTF

R. Shibaeva ¹ S. Khasanov ¹ L. Zorina ¹ S. Simonov ¹ I. Shevyakova ² L. Kushch ² L. Buravov ² E. Yagubskii ² S. Baudron ³ C. Meziere ³ P. Batail ³ J. Yamada ⁴

1 Institute of Solid State Physics of the Russian Academy of Sciences

2 Institute of Problems of Chemical Physics of RAS

3 CIMMA - Chimie, Ingénierie Moléculaire et Matériaux d'Angers

4 Himeji Institute of Technology, Department of Material Science

Abstract : The radical cation salts based on BDH-TTP and the mono- and diamide functionalized derivatives of EDT-TTF with the double charged nitroprusside anion [FeNO(CN)5]2- (NP): kappa -(BDH-TTP)4[NP]C6H5NO2 (1), kappa -(BDH-TTP)4[NP] (2), (BDH-TTP)2[NP] (3), alpha-[ EDT-TTF-CONH 2]4[NP] (4), beta -[ EDT-TTF-(CONH2)2]2[NP] 0.5(C6H5NO2)0.5 (5) have been synthesized. The crystal structures and transport properties of 1 - 5, as well as electronic band structures of 1and 2 have been studied.

Keywords : conductivity nitroprusside anion Organic conductors based on radical cation salts X-ray and band structure

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Chimie

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Exploitation of the photochromic nitroprusside anion [FeNO(CN)5]2- as counterion for constructing molecular conductors: The first radical cation salts based on BDH-TTP and the amide functionalized derivatives of EDT-TTF

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Exploitation of the photochromic nitroprusside anion [FeNO(CN)5]2- as counterion for constructing molecular conductors: The first radical cation salts based on BDH-TTP and the amide functionalized derivatives of EDT-TTF

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