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A self-assembled M2L4 cage incorporating electron-rich 9-(1,3-dithiol-2-ylidene)fluorene units

Abstract : An electron-rich redox-active M2L4 cage is depicted. The cage is constructed through coordination driven self-assembly of a 9-(1,3-dithiol-2-ylidene)fluorene bis-pyridyl ligand in the presence of the Pd(BF4)2(CH3CN)4 complex. The corresponding discrete structure has been fully characterized in the solution as well in the solid state (crystal structure), showing notably that each of the four ligands surrounding the cavity can be reversibly oxidized upon a one electron process.
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https://hal.univ-angers.fr/hal-02564444
Contributeur : Okina Université d'Angers <>
Soumis le : mardi 5 mai 2020 - 20:30:12
Dernière modification le : vendredi 28 août 2020 - 03:13:50

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Vincent Croué, Serhii Krykun, Magali Allain, Yohann Morille, Frédéric Aubriet, et al.. A self-assembled M2L4 cage incorporating electron-rich 9-(1,3-dithiol-2-ylidene)fluorene units. New Journal of Chemistry, Royal Society of Chemistry, 2017, 41 (9), pp.3238-3241. ⟨10.1039/C7NJ00062F⟩. ⟨hal-02564444⟩

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