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Article dans une revue

Spirobifluorene based small push-pull molecules for organic photovoltaic applications

Abstract : Four analogous push-pull systems have been synthesized. If the latter all involve the same electron rich diphenylamine termination (D) and π-conjugating spacer (p) they differ from their electron withdrawing groups (A) and more importantly by their linear or 3D structure. Indeed, two push-pull spirobifluorene derivatives, which present two perpendicular D-p-A systems by molecule, are compared to their linear analogues. After description of their syntheses, spectroscopic and electrochemical properties, comforted by theoretical calculations, are discussed and compared. Then, a preliminary evaluation of compounds as active materials in organic solar cells is presented and demonstrates the potential interest of spiro-based derivatives for organic photovoltaics.
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https://hal.univ-angers.fr/hal-02564473
Contributeur : Okina Université d'Angers <>
Soumis le : mardi 5 mai 2020 - 21:23:57
Dernière modification le : mercredi 14 octobre 2020 - 03:58:07

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Clément Dalinot, György Szalóki, Chloé Dindault, Olivier Segut, Lionel Sanguinet, et al.. Spirobifluorene based small push-pull molecules for organic photovoltaic applications. Dyes and Pigments, 2017, 140, pp.62-69. ⟨10.1016/j.dyepig.2017.01.034⟩. ⟨hal-02564473⟩

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