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Pyrene bisiminopyridine ligand and its zinc complex

Abstract : The synthesis of a pyrene bisiminopyridine ligand L was successfully accomplished by condensation between 1-aminopyrene and 2,6-pyridinecarboxaldehyde. The complexation of L with zinc triflate afforded a neutral metal complex formulated as [Zn(H2O)LCF3SO3)2].2Et2O. In the complex, the ligand is coordinated to zinc(II) through its three nitrogen atoms which form a distorted octahedral environment together with three oxygen atoms, two from the triflate anions and one from aqua ligand. Both compounds have been characterized using NMR, elemental analysis, mass spectrometry, electronic absorption (UV-Vis) and infrared. Luminescence properties of these compounds show an emission maxima at 412 nm, indicating a pyrene monomer emission.
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https://hal.univ-angers.fr/hal-02564503
Contributeur : Okina Université d'Angers <>
Soumis le : mardi 5 mai 2020 - 21:24:50
Dernière modification le : mardi 23 juin 2020 - 12:30:05

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Awatef Ayadi, Diana-G. Branzea, Haluk Dincalp, Nabil Zouari, Abdelkrim El-Ghayoury. Pyrene bisiminopyridine ligand and its zinc complex. Molecular Crystals and Liquid Crystals, Taylor & Francis, 2016, 628 (1), pp.188-197. ⟨10.1080/15421406.2015.1137386⟩. ⟨hal-02564503⟩

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