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Article dans une revue
Indolino-Oxazolidine Acido- and Photochromic System Investigated by NMR and Density Functional Theory Calculations
Abstract : Three addressable indolino-oxazolidine units connected through an isomerizable double bond to a substituted thiophene represent a smart example of a multiaddressable system whose reversible responses could be selectively activated on demand. Experimental and theoretical approaches to push forward the understanding of the system mechanism and set pathways to design optimized compounds for suitable application are here presented. NMR and UV–visible spectroscopies are used for structural and kinetic studies, while density functional theory (DFT) calculations pave the way to highlight energetic and electronic processes that are involved. Substitution and solvent effects toward the reactivity of the compounds are experimentally studied and combined with theoretical calculations. The most efficient and selective stimuli to travel between the four possible states resulting from the ring-opening of indolino[2,1-b]oxazolidine (generally referenced as BOX) derivatives and the trans–cis isomerization of the ethylenic junction are elucidated.
https://hal.univ-angers.fr/hal-02564565
Contributeur : Okina Université d'Angers <>
Soumis le : mardi 5 mai 2020 - 22:14:03
Dernière modification le : jeudi 28 mai 2020 - 10:16:02
Contributeur : Okina Université d'Angers <>
Soumis le : mardi 5 mai 2020 - 22:14:03
Dernière modification le : jeudi 28 mai 2020 - 10:16:02
