Multi-property isotropic intermolecular potentials and predicted spectral lineshapes of collision-induced absorption (CIA), collision-induced light scattering (CILS) and collision-induced hyper-Rayleigh scattering (CIHR) for H2 –Ne, −Kr and −Xe - Université d'Angers Accéder directement au contenu
Article Dans Une Revue Journal of Quantitative Spectroscopy and Radiative Transfer Année : 2018

Multi-property isotropic intermolecular potentials and predicted spectral lineshapes of collision-induced absorption (CIA), collision-induced light scattering (CILS) and collision-induced hyper-Rayleigh scattering (CIHR) for H2 –Ne, −Kr and −Xe

Résumé

Quantum mechanical lineshapes of collision-induced absorption (CIA), collision-induced light scattering (CILS) and collision-induced hyper-Rayleigh scattering (CIHR) at room temperature (295 K) are computed for gaseous mixtures of molecular hydrogen with neon, krypton and xenon. The induced spectra are detected using theoretical values for induced dipole moment, pair-polarizability trace and anisotropy, hyper-polarizability and updated intermolecular potentials. Good agreement is observed for all spectra when the literature and the present potentials which are constructed from the transport and thermo-physical properties are used.

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Dates et versions

hal-02572822 , version 1 (13-05-2020)

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M.S.A. El-Kader, Jean-Luc Godet, Magnus Gustafsson, George Maroulis. Multi-property isotropic intermolecular potentials and predicted spectral lineshapes of collision-induced absorption (CIA), collision-induced light scattering (CILS) and collision-induced hyper-Rayleigh scattering (CIHR) for H2 –Ne, −Kr and −Xe. Journal of Quantitative Spectroscopy and Radiative Transfer, 2018, 209, pp.232-242. ⟨10.1016/j.jqsrt.2018.01.035⟩. ⟨hal-02572822⟩

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