The overall efficiency of a PV system is strongly affected by the PV cell raw materials. Since a reliable renewable energy source is expected to produce maximum power with longest lifetime and minimum errors, a critical aspect to bear in mind is the occurrence of PV faults according to raw material types. The different failure scenarios occurring in PV system, decrease its output power, reduce its life expectancy and ban the system from meeting load demands, yielding to severe consecutive blackouts. This paper aims first to present different core materials types, material based fault occurring on the PV cell level and consequently the fault detection techniques corresponding to each fault type.