Evidence for an isotropic signature in double vibrational collision-induced Raman scattering: A point-polarizable molecule model - Université d'Angers Accéder directement au contenu
Article Dans Une Revue Physical Review A Année : 2010

Evidence for an isotropic signature in double vibrational collision-induced Raman scattering: A point-polarizable molecule model

Michel Chrysos
  • Fonction : Auteur
  • PersonId : 991927
I.-A. Verzhbitskiy
  • Fonction : Auteur

Résumé

The particularly weak isotropic spectrum of the recently reported [ Verzhbitskiy et al. Phys. Rev. A 81 012702 (2010)] nearly depolarized collision-induced Raman scattering band SF6(ν1)+N2(ν1) at room temperature was obtained and is presented here. The spectrum was extracted from high-quality measurements of two independent incident-field polarization scattering components. Its zero-order moment was found to be about 200 times smaller than that of its anisotropic counterpart. Agreement, both in spectral shape and in intensity, was found with predictions based on the dipole-induced dipole polarization model once corrected for the very substantial back-induction, dispersion, and dipole-induced quadrupole-induced dipole interaction mechanisms, all of which were considered within the model framework of two point-polarizable molecules. Quantum-mechanical calculations revealed a large contribution from bound and predissociating dimers that amounts to more than one-third of the total isotropic scattering intensity.

Domaines

Chimie
Fichier principal
Vignette du fichier
chrysos2010.pdf (554.82 Ko) Télécharger le fichier
Origine : Fichiers éditeurs autorisés sur une archive ouverte

Dates et versions

hal-03027824 , version 1 (24-05-2021)

Identifiants

Citer

Michel Chrysos, I.-A. Verzhbitskiy. Evidence for an isotropic signature in double vibrational collision-induced Raman scattering: A point-polarizable molecule model. Physical Review A, 2010, 81 (4), pp.042705. ⟨10.1103/PhysRevA.81.042705⟩. ⟨hal-03027824⟩
18 Consultations
28 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More