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Article dans une revue

Tetrathiafulvalene-Oxazolines (TTF-Ox) And Derivatives: Valuable Precursors For Chiral Conductors And Electroactive Complexes

Abstract :

The synthesis and structural characterization of racemic and enantiopure tetrathiafulvalene-oxazolines (TTF-OX) derivatives, with an emphasis on several key features, are reviewed. These compounds can serve as precursors for conducting chiral materials, but also as electroactive ligands for transition metal complexes. Crystalline conducting molecular materials have been obtained uponelectrocrystallization of some of the donors, such as the first complete series of mixed-valence metallic salts based on chiral tetrathiafulvalenes, bearing the (R)-, (S)-, or racemic (±)-methyl–oxazoline heterocycle and the AsF6– monoanion. Transition metal complexes containing electroactive TTF-OX ligands have been prepared as well. Palladium and iridium complexes containing TTF-phosphino-oxazoline (TTF-PHOX) ligands have been applied in two homogeneous catalytic processes.

Type de document :
Article dans une revue
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https://hal.univ-angers.fr/hal-03027836
Contributeur : Okina Université d'Angers <>
Soumis le : vendredi 27 novembre 2020 - 12:28:51
Dernière modification le : samedi 28 novembre 2020 - 03:27:37

Identifiants

  • HAL Id : hal-03027836, version 1
  • OKINA : ua1929

Citation

Narcis Avarvari. Tetrathiafulvalene-Oxazolines (TTF-Ox) And Derivatives: Valuable Precursors For Chiral Conductors And Electroactive Complexes. Revue Roumaine de Chimie, 2009, 54 (6), pp.411 - 420. ⟨hal-03027836⟩

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