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Spectrophotometric Study of Cobalt (II) Chlorocomplexes in Methanol in the Visible Domain
Abstract : Cobalt(II) chlorocomplexes were studied in a polar protic solvent namely methanol at 25°C. The spectrophotometric technique in the visible region was used. The studied equilibrium is: Co 2+ + j Cl - CoCl j ↔ (j-2)- . Formation of three chlorocomplexes and a structural modification (Oh → Td) were obtained from recorded spectra analysis. The stability of CoCl + was studied by the graphical method of Kruh and the overall stability constants were calculated with the SIRKO program based on the least-square method. Different models were tested and the model was retained for which the best values are: log β1 = 0.92, log β2 = 1.31 and log β3 = 1.08.
https://hal.univ-angers.fr/hal-03253575
Contributeur : Mustayeen Khan <>
Soumis le : mardi 8 juin 2021 - 13:02:03
Dernière modification le : mardi 15 juin 2021 - 14:24:00
Contributeur : Mustayeen Khan <>
Soumis le : mardi 8 juin 2021 - 13:02:03
Dernière modification le : mardi 15 juin 2021 - 14:24:00
