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Article dans une revue

Extended triphenylamine conjugated systems derivatized by perfluorophenyl groups

Abstract :

Two triphenylamine derivatives bearing terminal perfluorophenyl groups have been synthesized. Their HOMO. LUMO levels and electronic band gap have been evaluated by spectroscopic and electrochemical measurements and rationalized with theoretical calculations. X-ray structure analysis of crystals allowed the observation of multiple intermolecular interactions due to the presence of the perfluorophenyl pendant groups. The multiplication of these interactions explains the differences between calculated (in gas phase) and observed (in solid states) structures. (C) 2011 Elsevier Ltd. All rights reserved.

Type de document :
Article dans une revue
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Soumis le : mercredi 15 septembre 2021 - 10:26:05
Dernière modification le : jeudi 9 décembre 2021 - 15:46:06



Emilie Ripaud, Charlotte Mallet, Magali Allain, Philippe Leriche, Pierre Frère, et al.. Extended triphenylamine conjugated systems derivatized by perfluorophenyl groups. Tetrahedron Letters, Elsevier, 2011, 52 (49), pp.6573-6577. ⟨10.1016/j.tetlet.2011.09.129⟩. ⟨hal-03344591⟩



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