Exact Low‐Order Classical Moments in Collision‐Induced Bands by Linear Rotors: CO2‐CO2
Résumé
Analytic, classically‐exact formulas are derived for the zeroth and second moments of the IR and Raman bands induced by collisions of two linear molecules. The V 3 Raman and far IR rototranslational bands by CO 2 ‐ CO 2 are analyzed and shown to be induced solely by classical long‐range interactions.