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Zinc(II) and copper(II) complexes with benzothiadiazole Schiff-base ligands †

Abstract : The ligand (2-[4-(2,1,3-benzothiadiazole)imino]methyl-phenol) HL 1 containing the electron poor benzothiadiazole (BTD) unit, conveniently prepared by condensation of 4-amino-2,1,3benzothiadiazole and salicylaldehyde, has been structurally characterized by single crystal X-ray diffraction. Two energy minima have been determined, by DFT calculations, for HL 1 and for its ortho-vanillin analogue HL 2 , corresponding either to the conformer observed in the solid state or to the chelating tridentate form. TD-DFT calculations have been performed on HL 1 and HL 2 in order to assign their experimental UV-visible absorption bands. Reaction of HL 1 and HL 2 with copper (II) hexafluoroacetylacetonate (hfac), zinc (II) hexafluoroacetylacetonate or zinc (II) acetate provided the neutral complexes [Cu(L 1)(hfac)] (1), [Zn(L 1)2] (2), [Cu(L 2)2] (3) and [Zn(L 2)2] (4) which were structurally characterized, with a focus on the coordination sphere of the metal centre and on the intermolecular interactions. The UV-visible absorption properties of the Zn(II) complexes 2 and 4 have been experimentally and theoretically investigated and compared to those of the ligands. Finally, the cryomagnetic study of 1 and 3 in the temperature range 2.0-295.0 K reveals a Curie-Weiss law behaviour with very weak intermolecular antiferromagnetic interactions in the low temperature region.
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Soumis le : mercredi 16 novembre 2022 - 10:57:52
Dernière modification le : jeudi 17 novembre 2022 - 04:12:58


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Nataliya Plyuta, Thomas Cauchy, Andreas Hauser, Francesc Lloret, Miguel Julve, et al.. Zinc(II) and copper(II) complexes with benzothiadiazole Schiff-base ligands †. Polyhedron, 2022, 224, pp.115994. ⟨10.1016/j.poly.2022.115994⟩. ⟨hal-03855098⟩



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